Likelihood Adaptively Modified Penalties

A new family of penalty functions, adaptive to likelihood, is introduced for model selection in general regression models. It arises naturally through assuming certain types of prior distribution on the regression parameters. To study stability properties of the penalized maximum likelihood estimator, two types of asymptotic stability are defined. Theoretical properties, including the parameter estimation consistency, model selection consistency, and asymptotic stability, are established under suitable regularity conditions. An efficient coordinate-descent algorithm is proposed. Simulation results and real data analysis show that the proposed method has competitive performance in comparison with existing ones.Comment: 42 pages, 4 figure

Polyoxometalate (POM)-layered double hydroxides (LDH) composite materials: design and catalytic applications

Layered double hydroxides (LDHs) are an important large class of two-dimensional (2D) anionic lamellar materials that possess flexible modular structure, facile exchangeability of inter-lamellar guest anions and uniform distribution of metal cations in the layer. Owing to the modular accessible gallery and unique inter-lamellar chemical environment, polyoxometalates (POMs) intercalated with LDHs has shown a vast array of physical properties with applications in environment, energy, catalysis, etc. Here we describe how polyoxometalate clusters can be used as building components for the construction of systems with important catalytic properties. This review article mainly focuses on the discussion of new synthetic approaches developed recently that allow the incorporation of the element of design in the construction of a fundamentally new class of materials with pre-defined functionalities in catalytic applications. Introducing the element of design and taking control over the finally observed functionality we demonstrate the unique opportunity for engineering materials with modular properties for specific catalytic applications

Rational design of a polyoxometalate intercalated layered double hydroxide: highly efficient catalytic epoxidation of allylic alcohols under mild and solvent-free conditions

Intercalation catalysts, owing to their modular and accessible gallery and unique interlamellar chemical environment, have shown wide application in various catalytic reactions. However, the poor mass transfer between the active components of the intercalated catalysts and organic substrates is one of the challenges that limit their further application. Herein, we have developed a novel heterogeneous catalyst by intercalating the polyoxometalate (POM) of Na9LaW10O36⋅32 H2O (LaW10) into layered double hydroxides (LDHs), which have been covalently modified with ionic liquids (ILs). The intercalation catalyst demonstrates high activity and selectivity for the epoxidation of various allylic alcohols in the presence of H2O2. For example, trans-2-hexen-1-ol undergoes up to 96 % conversion and 99 % epoxide selectivity at 25 °C in 2.5 h. To the best of our knowledge, the Mg3Al−ILs−C8−LaW10 composite material constitutes one of the most efficient heterogeneous catalysts for the epoxidation of allylic alcohols (including the hydrophobic allylic alcohols with long alkyl chains) reported so far

Developmental differences in the structure of executive function in middle childhood and adolescence

Although it has been argued that the structure of executive function (EF) may change developmentally, there is little empirical research to examine this view in middle childhood and adolescence. The main objective of this study was to examine developmental changes in the component structure of EF in a large sample (N = 457) of 7–15 year olds. Participants completed batteries of tasks that measured three components of EF: updating working memory (UWM), inhibition, and shifting. Confirmatory factor analysis (CFA) was used to test five alternative models in 7–9 year olds, 10–12 year olds, and 13–15 year olds. The results of CFA showed that a single-factor EF model best explained EF performance in 7–9-year-old and 10–12-year-old groups, namely unitary EF, though this single factor explained different amounts of variance at these two ages. In contrast, a three-factor model that included UWM, inhibition, and shifting best accounted for the data from 13–15 year olds, namely diverse EF. In sum, during middle childhood, putative measures of UWM, inhibition, and shifting may rely on similar underlying cognitive processes. Importantly, our findings suggest that developmental dissociations in these three EF components do not emerge until children transition into adolescence. These findings provided empirical evidence for the development of EF structure which progressed from unity to diversity during middle childhood and adolescence

Adaptive Synchronization of Nonlinearly Parameterized Complex Dynamical Networks with Unknown Time-Varying Parameters

A new adaptive learning control approach is proposed for a class of nonlinearly parameterized complex dynamical networks with unknown time-varying parameters. By using the parameter separation and reparameterization technique, the adaptive learning laws of periodically time-varying and constant parameters and an adaptive control strategy are designed to ensure the asymptotic convergence of the synchronization error in the sense of square error norm. Then, a sufficient condition of the synchronization is given by constructing a composite energy function. Finally, an example of the complex network is used to verify the effectiveness of proposed approach

Extracting Geospatial Information from Social Media Data for Hazard Mitigation, Typhoon Hato as Case Study (Short Paper)

With social media widely used for interpersonal communication, it has served as one important channel for information creation and propagation especially during hazard events. Users of social media in hazard-affected area can capture and upload hazard information more timely by portable and internet-connected electric devices such as smart phones or tablet computers equipped with (Global Positioning System) GPS devices and cameras. The information from social media(e.g. Twitter, facebook, sina-weibo, WebChat, etc.) contains a lot of hazard related information including texts, pictures, and videos. Most important thing is that a fair proportion of these crowd-sourcing information is valuable for the geospatial analysis in Geographic information system (GIS) during the hazard mitigation process. The geospatial information (position of observer, hazard-affected region, status of damages, etc) can be acquired and extracted from social media data. And hazard related information could also be used as the GIS attributes. But social media data obtained from crowd-sourcing is quite complex and fragmented on format or semantics. In this paper, we introduced the method how to acquire and extract fine-grained hazard damage geospatial information. According to the need of hazard relief, we classified the extracted information into eleven hazard loss categories and we also analyzed the public\u27s sentiment to the hazard. The 2017 typhoon "Hato" was selected as the case study to test the method introduced

TESTING FOR COMPLETE PASS-THROUGH OF EX ASS-THROUGH OF EXCHANGE RA ANGE RATE WITHOUT TRADE BARRIERS

The objective of this paper is to test whether the complete pass-through of exchange rate exists when there are almost no transaction costs and in the environment of competitive market. In general, the literature claims that the pass-through of exchange rate is incomplete due to imperfect market, i.e. the presence of transaction costs and imperfect competition. The quasi-experimental case of the food import to Hong Kong from Mainland China is considered in the analysis. The results show that the pass-through of the exchange rate of Chinese RMB against to US dollar to Hong Kong\u27s food import price is complete in long-run equilibrium. Besides, the short-run adjustment significantly contributes to correcting the deviation from the long-run pass-through effect. Moreover, the complete pass-through still exists after accounting for the effects of asymmetry and volatility. Therefore, this paper contributes to the literature by providing empirical evidence that the complete pass-through of exchange rate can exist in the real world

Summary of the Frontier Introduction of Preparation of Secondary Metabolites in Plant Cell Culture

Plant cell culture technology is a technology that applies the research results of cell engineering to produce plant biological products at the cellular level. In recent years, the secondary metabolites of plants have attracted more and more attention. The use of plant cell culture technology is a fast and efficient method of producing secondary metabolites